CAS: 934047-83-3|1, 3-Bis (cyanomethyl) imidazolium Chloride

Taw qhia ntawm CAS: 934047-83-3|1, 3-Bis (cyanomethyl) imidazolium chloride

1,3-bis(cyanomethyl)-1H-imidazol-3-ium chloride, tseem hu ua Dicyclohexylcarbodiimide (DCC), yog cov tshuaj reagent siv dav hauv cov organic synthesis. Nws yog dawb crystalline khoom uas yog soluble nyob rau hauv polar solvents xws li dej, ethanol, thiab acetone. DCC feem ntau yog siv los qhib carboxylic acids rau peptide synthesis, nrog rau cov synthesis ntawm esters, amides, thiab lwm yam organic compounds.

Specification of CAS: 934047-83-3|1, 3-Bis (cyanomethyl) imidazolium chloride

Kev Tshawb Fawb Daim Ntawv Thov CAS: 934047-83-3|1, 3-Bis (cyanomethyl) imidazolium chloride

Hais txog Hlau N-Heterocyclic Carbene Complexes: Txoj kev tshawb no tsom mus rau kev sib txuas ntawm hydrophilic N-heterocyclic carbene (NHC) ligand precursors ntsig txog 1,3-bis(cyanomethyl)-1H-imidazol-3-ium chloride. Cov precursors no yog siv los ua ke cov carbene complexes ntawm nyiaj (I), tooj liab (I), thiab kub (I), uas qhia cytotoxic zog tiv thaiv ntau yam tib neeg cov kab mob qog noj ntshav, suav nrog cisplatin-sensitive thiab-resistant hlwb. Cov nyiaj (I) txoj haujlwm tseem ceeb heev, thiab cov kub (I) thiab nyiaj (I) carbene complexes kuj pom muaj peev xwm inhibit enzyme thioredoxin reductase (TrxR) ntawm nanomolar concentrations (Pellei li al., 2012).

Elusive Dawb Bisimino-N-heterocyclic Carbene thiab Nws Rearrangement los ntawm C-C Coupling: Qhov kev tshawb fawb no nthuav tawm cov synthesis ntawm cov muaj peev xwm pincer-type N-heterocyclic carbene precursor ntsev. Txoj kev tshawb no tshawb txog cov qauv thiab spectroscopic cov khoom ntawm cov tebchaw thiab lawv cov kev cuam tshuam nrog iridium(I) thiab chromium(II) complexes (Liu li al., 2013).

Ib lub raj mis Imidazole-raws li Radical raws li Ib Leeg Electron Transfer Reagent: Txoj kev tshawb no qhia txog qhov tsim ntawm thawj tus yam ntxwv ntawm imidazole-raws li radical, uas tau tsim los ua ib qho kev hloov hluav taws xob nkaus xwb. Cov radical no tau siv ntau yam kev hloov pauv hauv cov organic, xws li kev ua kom muaj aryl-halide daim ntawv cog lus thiab catalytic txo CO2 rau methoxyborane nyob rau hauv ib puag ncig puag ncig (Das li al., 2020).

Synthesis thiab Fluorescence Properties of , ′-Bis(substituted-benzylidene)cycloalkanones Catalyzed by 1-Methyl-3(2-(sulfooxy)ethyl)-1H-imidazol{{7 }}Chloride: Daim ntawv no tshawb fawb txog kev sib txuas ntawm , '-Bis (hloov-benzylidene) cycloalkanones los ntawm cov kuab tshuaj tsis muaj cross-aldol condensation catalyzed los ntawm ib tug derivative ntawm 1,3-bis(cyanomethyl)-1H-imidazol -3-ium chloride. Txoj kev tshawb no tseem tshawb xyuas qhov cuam tshuam ntawm qhov loj ntawm cycloalkanone ntawm fluorescence emission ntawm cov khoom (Wan li al., 2010).

Electrochemical Reduction ntawm Imidazolium Cation: Qhov kev tshawb fawb no piav qhia txog cov tshuaj electrochemical thiab tshuaj txo qis ntawm 1,3-bis(2,4,6-trimethylphenyl) imidazolium chloride los tsim cov nucleophilic carbene. Cov carbene tau pom tias muaj kev sib raug zoo nrog thiab tsis tu ncua hauv ionic kua tetradecyl (trihexyl) phosphonium chloride (Gorodetsky li al., 2004).

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